| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. Smyslov vs Botvinnik |
 | 0-1 | 62 |
1958 |
Botvinnik-Smyslov World Championship Rematch | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 2. Smyslov vs Botvinnik |
 | 0-1 | 66 |
1958 |
Botvinnik-Smyslov World Championship Rematch | B19 Caro-Kann, Classical |
| 3. Smyslov vs Botvinnik |
 | 1-0 | 55 |
1958 |
Botvinnik-Smyslov World Championship Rematch | B12 Caro-Kann Defense |
| 4. Smyslov vs Botvinnik |
 | ½-½ | 49 |
1958 |
Botvinnik-Smyslov World Championship Rematch | B10 Caro-Kann |
| 5. Smyslov vs Botvinnik |
 | 1-0 | 35 |
1958 |
Botvinnik-Smyslov World Championship Rematch | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 6. M Nurmamedov vs Botvinnik |
 | 0-1 | 24 |
1959 |
Russia | B15 Caro-Kann |
| 7. Tal vs Botvinnik |
 | ½-½ | 41 |
1960 |
Tal-Botvinnik World Championship Match | B18 Caro-Kann, Classical |
| 8. Tal vs Botvinnik |
 | 1-0 | 52 |
1960 |
Tal-Botvinnik World Championship Match | B18 Caro-Kann, Classical |
| 9. Tal vs Botvinnik |
 | 0-1 | 58 |
1960 |
Tal-Botvinnik World Championship Match | B18 Caro-Kann, Classical |
| 10. Tal vs Botvinnik |
 | ½-½ | 43 |
1960 |
Tal-Botvinnik World Championship Match | B18 Caro-Kann, Classical |
| 11. Tal vs Botvinnik |
 | ½-½ | 37 |
1960 |
Tal-Botvinnik World Championship Match | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 12. Tal vs Botvinnik |
 | 1-0 | 41 |
1960 |
Tal-Botvinnik World Championship Match | B18 Caro-Kann, Classical |
| 13. Tal vs Botvinnik |
 | ½-½ | 121 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 14. Tal vs Botvinnik |
 | 1-0 | 29 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 15. Tal vs Botvinnik |
 | ½-½ | 41 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 16. Tal vs Botvinnik |
 | 1-0 | 45 |
1961 |
Tal-Botvinnik World Championship Return Match | B18 Caro-Kann, Classical |
| 17. Tal vs Botvinnik |
 | ½-½ | 90 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 18. Tal vs Botvinnik |
 | ½-½ | 33 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 19. Tal vs Botvinnik |
 | 0-1 | 42 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 20. Tal vs Botvinnik |
 | ½-½ | 25 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 21. Tal vs Botvinnik |
 | 0-1 | 41 |
1961 |
Tal-Botvinnik World Championship Return Match | B12 Caro-Kann Defense |
| 22. J Johansson vs Botvinnik |
| ½-½ | 41 |
1962 |
Bulgaria | B10 Caro-Kann |
| 23. B E Horberg vs Botvinnik |
 | 0-1 | 30 |
1962 |
Sweden | B16 Caro-Kann, Bronstein-Larsen Variation |
| 24. V Ciocaltea vs Botvinnik |
| 0-1 | 28 |
1964 |
Israel | B18 Caro-Kann, Classical |
| 25. Karpov vs Botvinnik |
 | ½-½ | 42 |
1964 |
Moscow clock simul | B15 Caro-Kann |