| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. S Volkov vs Aronian |
| 1-0 | 55 |
1996 |
RUS-Cup2 | D91 Grunfeld, 5.Bg5 |
| 2. S Volkov vs Aronian |
| 1-0 | 43 |
1996 |
RUS-Cup3 | D91 Grunfeld, 5.Bg5 |
| 3. S Volkov vs M Turov |
| ½-½ | 40 |
1998 |
RUS-Cup06 | D85 Grunfeld |
| 4. S Volkov vs Leko |
| ½-½ | 19 |
2000 |
FIDE World Ch | D91 Grunfeld, 5.Bg5 |
| 5. S Volkov vs A Timofeev |
| 1-0 | 55 |
2001 |
54th ch-RUS | D85 Grunfeld |
| 6. S Volkov vs Romanishin |
| ½-½ | 56 |
2001 |
TCh-ROM | D91 Grunfeld, 5.Bg5 |
| 7. S Volkov vs V Mikhalevski |
| 0-1 | 33 |
2001 |
ECC | D85 Grunfeld |
| 8. S Volkov vs A Timofeev |
| 1-0 | 43 |
2001 |
TCh-RUS | D85 Grunfeld |
| 9. S Volkov vs S Beshukov |
| 1-0 | 43 |
2002 |
Russian Championships | D85 Grunfeld |
| 10. S Volkov vs A Timofeev |
| 0-1 | 64 |
2003 |
56th Russian Championships | D97 Grunfeld, Russian |
| 11. S Volkov vs A Shomoev |
 | 1-0 | 30 |
2004 |
RUS-chT2 | D97 Grunfeld, Russian |
| 12. S Volkov vs M Turov |
| 0-1 | 69 |
2004 |
RUS-chT2 | D85 Grunfeld |
| 13. S Volkov vs Sutovsky |
| 0-1 | 42 |
2005 |
Aeroflot Open | D97 Grunfeld, Russian |
| 14. S Volkov vs Svidler |
| ½-½ | 12 |
2005 |
Russian Championship Superfinal | D97 Grunfeld, Russian |
| 15. S Volkov vs Van Wely |
| 1-0 | 45 |
2005 |
Aeroflot Open | D97 Grunfeld, Russian |
| 16. S Volkov vs Khalifman |
| 1-0 | 28 |
2005 |
Russian Team Championship | D97 Grunfeld, Russian |
| 17. S Volkov vs Shabanov |
| 1-0 | 31 |
2006 |
59th Russian Championship | D93 Grunfeld, with Bf4 & e3 |
| 18. S Volkov vs A Evdokimov |
| 1-0 | 73 |
2007 |
6th Aeroflot Festival | D85 Grunfeld |
| 19. S Volkov vs C Lupulescu |
| 1-0 | 60 |
2008 |
European Individual Championship | D97 Grunfeld, Russian |
| 20. S Volkov vs I Kurnosov |
| ½-½ | 54 |
2008 |
European Individual Championship | D97 Grunfeld, Russian |
| 21. S Volkov vs K Maslak |
| ½-½ | 38 |
2009 |
62nd Russian Championship Higher League | D91 Grunfeld, 5.Bg5 |
| 22. S Volkov vs I Kurnosov |
| 1-0 | 68 |
2009 |
62nd Russian Championship Higher League | D70 Neo-Grunfeld Defense |
| 23. S Volkov vs A Shimanov |
| ½-½ | 47 |
2009 |
62nd Russian Championship Higher League | D94 Grunfeld |
