| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. I A Nataf vs Motylev |
| 0-1 | 46 |
2003 |
EU-ch 4th | B12 Caro-Kann Defense |
| 2. Naiditsch vs Motylev |
 | 0-1 | 28 |
2006 |
Corus Wijk aan Zee Group B | B18 Caro-Kann, Classical |
| 3. M Gagunashvili vs Motylev |
| 0-1 | 73 |
2006 |
Corsica Masters | B14 Caro-Kann, Panov-Botvinnik Attack |
| 4. E Vorobiov vs Motylev |
| ½-½ | 15 |
2006 |
59th Russian Championship | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 5. Tiviakov vs Motylev |
| ½-½ | 40 |
2007 |
Corus | B10 Caro-Kann |
| 6. Karjakin vs Motylev |
 | ½-½ | 21 |
2007 |
Corus | B12 Caro-Kann Defense |
| 7. P Ponkratov vs Motylev |
| ½-½ | 17 |
2008 |
Moscow Open | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 8. K Szabo vs Motylev |
| 0-1 | 59 |
2008 |
Ordix Open | B14 Caro-Kann, Panov-Botvinnik Attack |
| 9. A Tukhaev vs Motylev |
 | ½-½ | 18 |
2008 |
European Individual Championship | B12 Caro-Kann Defense |
| 10. R Polzin vs Motylev |
| 0-1 | 45 |
2008 |
2008-2009 Bundesliga | B12 Caro-Kann Defense |
| 11. G Guseinov vs Motylev |
| ½-½ | 13 |
2008 |
Aeroflot Open | B18 Caro-Kann, Classical |
| 12. S Fedorchuk vs Motylev |
| ½-½ | 18 |
2008 |
2008-2009 Bundesliga | B18 Caro-Kann, Classical |
| 13. Caruana vs Motylev |
 | 0-1 | 36 |
2008 |
Aeroflot Open | B12 Caro-Kann Defense |
| 14. P Smirnov vs Motylev |
| ½-½ | 46 |
2008 |
61st Russian Championship Higher League | B18 Caro-Kann, Classical |
| 15. K Haznedaroglu vs Motylev |
| ½-½ | 43 |
2009 |
10th European Individual Championship | B18 Caro-Kann, Classical |
| 16. B Kalezic vs Motylev |
| 0-1 | 51 |
2009 |
10th European Individual Championship | B12 Caro-Kann Defense |
| 17. M Bartel vs Motylev |
| ½-½ | 24 |
2009 |
10th European Individual Championship | B12 Caro-Kann Defense |
| 18. V Zvjaginsev vs Motylev |
| ½-½ | 12 |
2010 |
European Individual Championships | B18 Caro-Kann, Classical |
| 19. D Petrosian vs Motylev |
| ½-½ | 50 |
2010 |
European Individual Championships | B14 Caro-Kann, Panov-Botvinnik Attack |
| 20. S Azarov vs Motylev |
 | 0-1 | 37 |
2010 |
Moscow Open | B12 Caro-Kann Defense |
| 21. O De la Riva Aguado vs Motylev |
| 0-1 | 42 |
2010 |
Chess Olympiad | B11 Caro-Kann, Two Knights, 3...Bg4 |
| 22. Svidler vs Motylev |
| ½-½ | 46 |
2011 |
Bundesliga | B13 Caro-Kann, Exchange |
| 23. Caruana vs Motylev |
| ½-½ | 34 |
2011 |
12th Karpov International | B12 Caro-Kann Defense |
| 24. T L Petrosian vs Motylev |
| ½-½ | 17 |
2011 |
Aeroflot Open | B18 Caro-Kann, Classical |
| 25. Lu Shanglei vs Motylev |
| ½-½ | 53 |
2012 |
Chinese League | B11 Caro-Kann, Two Knights, 3...Bg4 |