| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. M Turov vs Motylev |
| 1-0 | 51 |
1996 |
RUS-ch U20 | B22 Sicilian, Alapin |
| 2. M Turov vs Motylev |
| 0-1 | 43 |
1997 |
RUS-ch U20 | B22 Sicilian, Alapin |
| 3. M Turov vs Motylev |
| 0-1 | 65 |
1998 |
RUS-ch U20 | B22 Sicilian, Alapin |
| 4. I Yagupov vs Motylev |
| ½-½ | 29 |
1998 |
RUS-ch | B75 Sicilian, Dragon, Yugoslav Attack |
| 5. H Odeev vs Motylev |
| 0-1 | 51 |
1999 |
Geller Memorial (Cup Russia) | B34 Sicilian, Accelerated Fianchetto |
| 6. P Pisk vs Motylev |
 | 0-1 | 49 |
2000 |
V Ubeda Open | B22 Sicilian, Alapin |
| 7. E Vorobiov vs Motylev |
| ½-½ | 15 |
2000 |
Chigorin Memorial | B36 Sicilian, Accelerated Fianchetto |
| 8. Glek vs Motylev |
| ½-½ | 19 |
2001 |
open | B52 Sicilian, Canal-Sokolsky (Rossolimo) Attack |
| 9. I Sofronie vs Motylev |
| ½-½ | 75 |
2001 |
TCh-ROM | B31 Sicilian, Rossolimo Variation |
| 10. V Slovineanu vs Motylev |
| ½-½ | 33 |
2001 |
ECC | B23 Sicilian, Closed |
| 11. A Pridorozhni vs Motylev |
| 0-1 | 38 |
2001 |
TCh-RUS | B20 Sicilian |
| 12. M Dzhumaev vs Motylev |
| 0-1 | 32 |
2001 |
open | B53 Sicilian |
| 13. E Inarkiev vs Motylev |
 | 0-1 | 52 |
2002 |
Aeroflot Open | B72 Sicilian, Dragon |
| 14. E Prokopchuk vs Motylev |
| ½-½ | 52 |
2002 |
Aeroflot Open | B54 Sicilian |
| 15. Grigoriants vs Motylev |
| ½-½ | 10 |
2003 |
EU-ch 4th | B57 Sicilian |
| 16. Jobava vs Motylev |
| 1-0 | 53 |
2003 |
Dubai op 5th | B60 Sicilian, Richter-Rauzer |
| 17. Rublevsky vs Motylev |
| ½-½ | 53 |
2004 |
Corsica Masters | B52 Sicilian, Canal-Sokolsky (Rossolimo) Attack |
| 18. M Al-Modiahki vs Motylev |
| 0-1 | 52 |
2005 |
7th Dubai Open Chess Championship | B71 Sicilian, Dragon, Levenfish Variation |
| 19. I Kurnosov vs Motylev |
| 0-1 | 43 |
2005 |
6th European Individual Championship | B63 Sicilian, Richter-Rauzer Attack |
| 20. R Antonio vs Motylev |
 | ½-½ | 40 |
2005 |
HB Global Chess Challenge | B22 Sicilian, Alapin |
| 21. V Bachin vs Motylev |
| 0-1 | 57 |
2005 |
Russian Team Championship | B25 Sicilian, Closed |
| 22. I Khairullin vs Motylev |
| ½-½ | 18 |
2005 |
6th European Individual Championship | B22 Sicilian, Alapin |
| 23. J Friedel vs Motylev |
| 0-1 | 67 |
2005 |
HB Global Chess Challenge | B35 Sicilian, Accelerated Fianchetto, Modern Variation with Bc4 |
| 24. S Vokarev vs Motylev |
| ½-½ | 17 |
2005 |
Russian Team Championship | B52 Sicilian, Canal-Sokolsky (Rossolimo) Attack |
| 25. S Shivaji vs Motylev |
| 0-1 | 27 |
2005 |
HB Global Chess Challenge | B57 Sicilian |