| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. Motylev vs Tiviakov |
| 0-1 | 40 |
1998 |
RUS-ch | B75 Sicilian, Dragon, Yugoslav Attack |
| 2. Motylev vs Grischuk |
| 0-1 | 29 |
1998 |
RUS-ch | B30 Sicilian |
| 3. Motylev vs S Vokarev |
| 0-1 | 38 |
1999 |
Geller Memorial | B27 Sicilian |
| 4. Motylev vs E Alekseev |
| 0-1 | 28 |
2001 |
TCh-RUS | B48 Sicilian, Taimanov Variation |
| 5. Motylev vs Judit Polgar |
| 0-1 | 53 |
2001 |
2nd IECC | B90 Sicilian, Najdorf |
| 6. Motylev vs Judit Polgar |
 | 0-1 | 30 |
2002 |
European Club Cup | B32 Sicilian |
| 7. Motylev vs Gelfand |
 | 0-1 | 29 |
2002 |
Russia vs The Rest of the World | B90 Sicilian, Najdorf |
| 8. Motylev vs Dvoirys |
| 0-1 | 44 |
2003 |
56th Russian Championships | B90 Sicilian, Najdorf |
| 9. Motylev vs Topalov |
 | 0-1 | 53 |
2003 |
7th Corsica Open | B42 Sicilian, Kan |
| 10. Motylev vs A Korotylev |
 | 0-1 | 45 |
2004 |
Russian Championships 2004 | B63 Sicilian, Richter-Rauzer Attack |
| 11. Motylev vs Grischuk |
 | 0-1 | 34 |
2004 |
Russian Championships 2004 | B90 Sicilian, Najdorf |
| 12. Motylev vs Rublevsky |
| 0-1 | 57 |
2004 |
Corsica Masters | B46 Sicilian, Taimanov Variation |
| 13. Motylev vs H Hamdouchi |
| 0-1 | 47 |
2004 |
FIDE World Championship Knockout Tournament | B33 Sicilian |
| 14. Motylev vs M Palac |
| 0-1 | 43 |
2005 |
15th European Team Championship | B90 Sicilian, Najdorf |
| 15. Motylev vs Bu Xiangzhi |
 | 0-1 | 34 |
2005 |
2nd Sanjin Hotel Cup | B90 Sicilian, Najdorf |
| 16. Motylev vs R Wojtaszek |
 | 0-1 | 46 |
2005 |
6th European Individual Championship | B66 Sicilian, Richter-Rauzer Attack, 7...a6 |
| 17. Motylev vs Bologan |
 | 0-1 | 45 |
2006 |
Aeroflot Open | B90 Sicilian, Najdorf |
| 18. Motylev vs Judit Polgar |
 | 0-1 | 52 |
2007 |
Biel Chess Festival | B99 Sicilian, Najdorf, 7...Be7 Main line |
| 19. Motylev vs Anand |
 | 0-1 | 31 |
2007 |
Corus | B97 Sicilian, Najdorf |
| 20. Motylev vs Bu Xiangzhi |
 | 0-1 | 42 |
2007 |
World Chess Cup | B35 Sicilian, Accelerated Fianchetto, Modern Variation with Bc4 |
| 21. Motylev vs A Horvath |
 | 0-1 | 43 |
2008 |
Ordix Open | B48 Sicilian, Taimanov Variation |
| 22. Motylev vs Nijboer |
 | 0-1 | 35 |
2009 |
10th European Individual Championship | B67 Sicilian, Richter-Rauzer Attack, 7...a6 Defense, 8...Bd7 |
| 23. Motylev vs Jakovenko |
 | 0-1 | 25 |
2010 |
Poikovsky Tournament | B30 Sicilian |
| 24. Motylev vs Grischuk |
| 0-1 | 51 |
2010 |
ACP World Rapid Cup | B90 Sicilian, Najdorf |
| 25. Motylev vs Sutovsky |
 | 0-1 | 39 |
2010 |
Chess Olympiad | B97 Sicilian, Najdorf |