| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. Li Chao vs G Rohit |
| 1-0 | 49 |
2005 |
World Junior Championship (Boys) | B42 Sicilian, Kan |
| 2. Li Chao vs E Moradiabadi |
| ½-½ | 47 |
2005 |
World Junior Championship (Boys) | B42 Sicilian, Kan |
| 3. Li Chao vs M Paragua |
| 0-1 | 24 |
2005 |
3rd Pichay Cup Intl Open | B86 Sicilian, Fischer-Sozin Attack |
| 4. Li Chao vs V Papin |
| 1-0 | 46 |
2005 |
World Junior Championship (Boys) | B42 Sicilian, Kan |
| 5. Li Chao vs K Kuderinov |
| 1-0 | 38 |
2005 |
World Junior Championship (Boys) | B58 Sicilian |
| 6. Li Chao vs Wen Yang |
| ½-½ | 45 |
2006 |
World Junior Championship | B31 Sicilian, Rossolimo Variation |
| 7. Li Chao vs E Valeanu |
| ½-½ | 48 |
2006 |
World Junior Championship | B93 Sicilian, Najdorf, 6.f4 |
| 8. Li Chao vs D Brandenburg |
 | 1-0 | 40 |
2006 |
World Junior Championship | B67 Sicilian, Richter-Rauzer Attack, 7...a6 Defense, 8...Bd7 |
| 9. Li Chao vs M Al Sayed |
| ½-½ | 48 |
2007 |
Asian Individual Championship | B35 Sicilian, Accelerated Fianchetto, Modern Variation with Bc4 |
| 10. Li Chao vs Agrest |
| 1-0 | 72 |
2007 |
Scandinavian Chess Tournament | B23 Sicilian, Closed |
| 11. Li Chao vs L Evertsson |
| 1-0 | 47 |
2007 |
Scandinavian Chess Tournament | B40 Sicilian |
| 12. Li Chao vs J Catalino Sadorra |
| 1-0 | 30 |
2007 |
Manila op | B96 Sicilian, Najdorf |
| 13. Li Chao vs Grigoriants |
| ½-½ | 32 |
2007 |
6th Aeroflot Festival | B46 Sicilian, Taimanov Variation |
| 14. Li Chao vs V Aveskulov |
| 1-0 | 50 |
2008 |
Mindsports | B93 Sicilian, Najdorf, 6.f4 |
| 15. Li Chao vs A Brkic |
| 1-0 | 41 |
2008 |
World Junior Championship | B93 Sicilian, Najdorf, 6.f4 |
| 16. Li Chao vs S Maze |
| 1-0 | 41 |
2008 |
2008 Olympiad | B30 Sicilian |
| 17. Li Chao vs P Leito |
| 1-0 | 37 |
2008 |
Mindsports | B83 Sicilian |
| 18. Li Chao vs T Sanikidze |
| 1-0 | 44 |
2008 |
World Junior Championship | B63 Sicilian, Richter-Rauzer Attack |
| 19. Li Chao vs A Zhigalko |
| 1-0 | 33 |
2008 |
2008 Olympiad | B62 Sicilian, Richter-Rauzer |
| 20. Li Chao vs Y Kryvoruchko |
| 1-0 | 19 |
2008 |
Mindsports | B40 Sicilian |
| 21. Li Chao vs Lim Yee Weng |
| 1-0 | 44 |
2008 |
Malaysian Open | B25 Sicilian, Closed |
| 22. Li Chao vs M Leon Hoyos |
| ½-½ | 49 |
2008 |
World Junior Championship | B27 Sicilian |
| 23. Li Chao vs W Li |
| 1-0 | 60 |
2008 |
Dubai Open | B42 Sicilian, Kan |
| 24. Li Chao vs K Nadig |
| 1-0 | 22 |
2008 |
Malaysian Open | B96 Sicilian, Najdorf |
| 25. Li Chao vs Negi |
| 0-1 | 64 |
2008 |
World Junior Championship | B90 Sicilian, Najdorf |