| Game |
| Result | Moves |
Year |
Event/Locale | Opening |
| 1. T Nyback vs Li Chao |
 | 1-0 | 68 |
2005 |
World Junior Championship (Boys) | A17 English |
| 2. Li Chao vs K Kuderinov |
| 1-0 | 38 |
2005 |
World Junior Championship (Boys) | B58 Sicilian |
| 3. Li Chao vs G Rohit |
| 1-0 | 49 |
2005 |
World Junior Championship (Boys) | B42 Sicilian, Kan |
| 4. Li Chao vs V Papin |
| 1-0 | 46 |
2005 |
World Junior Championship (Boys) | B42 Sicilian, Kan |
| 5. N Mamedov vs Li Chao |
| 1-0 | 39 |
2005 |
World Junior Championship (Boys) | B90 Sicilian, Najdorf |
| 6. V Laznicka vs Li Chao |
| 1-0 | 63 |
2005 |
World Junior Championship (Boys) | B52 Sicilian, Canal-Sokolsky (Rossolimo) Attack |
| 7. Stellwagen vs Li Chao |
| 1-0 | 35 |
2006 |
World Junior Championship | C95 Ruy Lopez, Closed, Breyer |
| 8. Li Chao vs Wang Hao |
| 1-0 | 55 |
2006 |
World Junior Championship | B01 Scandinavian |
| 9. Li Chao vs D Sengupta |
| 1-0 | 45 |
2006 |
World Junior Championship | C16 French, Winawer |
| 10. Li Chao vs D Brandenburg |
| 1-0 | 40 |
2006 |
World Junior Championship | B67 Sicilian, Richter-Rauzer Attack, 7...a6 Defense, 8...Bd7 |
| 11. Li Chao vs A Gorovets |
| 1-0 | 40 |
2006 |
World Junior Championship | B03 Alekhine's Defense |
| 12. W So vs Li Chao |
| 1-0 | 22 |
2006 |
3rd Singapore Masters Chess Open | C47 Four Knights |
| 13. A Kim vs Li Chao |
| 1-0 | 57 |
2006 |
World Junior Championship | B90 Sicilian, Najdorf |
| 14. Wang Yue vs Li Chao |
| 1-0 | 44 |
2007 |
zt 3.5 | A16 English |
| 15. Li Chao vs Zhong Zhang |
| 1-0 | 33 |
2007 |
Malaysian Open Tt | C58 Two Knights |
| 16. G N Gopal vs Li Chao |
| 1-0 | 38 |
2007 |
Asian Individual Championship | B90 Sicilian, Najdorf |
| 17. Vallejo-Pons vs Li Chao |
| 1-0 | 34 |
2007 |
6th Aeroflot Festival | B20 Sicilian |
| 18. Li Chao vs R Wang |
| 1-0 | 60 |
2007 |
Malaysian Open Tt | C51 Evans Gambit |
| 19. Li Chao vs T Wedberg |
| 1-0 | 70 |
2007 |
Scandinavian Chess Tournament | C58 Two Knights |
| 20. Li Chao vs H Nouri |
| 1-0 | 36 |
2007 |
Malaysian Open Tt | C10 French |
| 21. Li Chao vs Agrest |
| 1-0 | 72 |
2007 |
Scandinavian Chess Tournament | B23 Sicilian, Closed |
| 22. Li Chao vs Hoang Thong Tu |
| 1-0 | 34 |
2007 |
Asian Individual Championship | C16 French, Winawer |
| 23. Li Chao vs P Einar |
| 1-0 | 28 |
2007 |
Scandinavian Chess Tournament | C10 French |
| 24. Li Chao vs J Catalino Sadorra |
| 1-0 | 30 |
2007 |
Manila op | B96 Sicilian, Najdorf |
| 25. T Batchuluun vs Li Chao |
| 1-0 | 40 |
2007 |
Asian Individual Championship | A15 English |
